Reactivity of 2-acylaminoacrylates with ketene diethyl acetal;: [2+2] cycloadditions vs. tandem condensations
Reactivity of 2-acylaminoacrylates with ketene diethyl acetal;: [2+2] cycloadditions vs. tandem condensations
复制标题
DOI：
10.1039/b302000b
复制
发表时间：
2003-01-01
影响因子：
4.9
通讯作者：
Peregrina, JM
中科院分区：
文献类型：
--
作者：
Avenoza, A;Busto, JH;Peregrina, JM
The reactivity of 2-acylaminoacrylates with ketene diethyl acetal can be modulated by means of thermal conditions to yield cyclobutanes for the preparation of protected beta-hydroxycyclobutane-alpha-amino acids, or catalytic conditions that yield cyclohexanes by tandem condensations to obtain interesting building blocks that are alternatives to Danishefsky's diene.
