ELECTROGENERATED CHEMI-LUMINESCENCE .41. ELECTROGENERATED CHEMI-LUMINESCENCE AND CHEMI-LUMINESCENCE OF THE RU(2,2'-BPY)3(2+)-S2O82- SYSTEM IN ACETONITRILE WATER SOLUTIONS
ELECTROGENERATED CHEMI-LUMINESCENCE .41. ELECTROGENERATED CHEMI-LUMINESCENCE AND CHEMI-LUMINESCENCE OF THE RU(2,2'-BPY)3(2+)-S2O82- SYSTEM IN ACETONITRILE WATER SOLUTIONS
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DOI：
10.1021/ja00389a001
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发表时间：
1982-01-01
影响因子：
15
通讯作者：
BARD, AJ
中科院分区：
文献类型：
--
作者：
WHITE, HS;BARD, AJ
描述了电生Ru (bpy) 3+与S2Og2~还原过程中产生的强氧化中间体SOT·在乙腈-水溶液（体积比为1:1）中产生的电生化学发光（eel）。橙色发光（Xmax= 625 nm）对应于Ru (bpy) 32+*的发光。相对强度是S2082~浓度的函数，对于1 mM Ru (bpy) 32+溶液，最大强度为15 ~ 20 mM S2082~。
The electrogenerated chemiluminescence (eel) produced in acetonitrile-water solutions (1: 1 by volume) by the reaction of electrogenerated Ru (bpy) 3+ with the strongly oxidizing intermediate, SOT·, generated during reduction of S2Og2~ is described. The orange luminescence (Xmax= 625 nm) corresponds to emission from Ru (bpy) 32+*. The relative eel intensity is a function of S2082~ concentration, and for a 1 mM Ru (bpy) 32+ solution the maximum eel intensity was obtained at 15-20 mM S2082-.