Mg0-promoted selective C-F bond cleavage of trifluoromethyl ketones:: a convenient method for the synthesis of 2,2-difluoro enol silanes
Mg0-promoted selective C-F bond cleavage of trifluoromethyl ketones:: a convenient method for the synthesis of 2,2-difluoro enol silanes
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DOI：
10.1039/a903681d
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发表时间：
1999-07-21
影响因子：
4.9
通讯作者：
Uneyama, K
中科院分区：
文献类型：
--
作者：
Amii, H;Kobayashi, T;Uneyama, K
在TMSCl存在下，通过Mg-0促进的三氟甲基酮的选择性脱附，容易地制备2，2-二氟烯醇硅醚，这涉及C-F键断裂。
2,2-Difluoro enol silyl ethers were readily prepared by Mg-0 promoted selective defluorination of trifluoromethyl ketones in the presence of TMSCl, which involves C-F bond cleavage.