The voltammetric response of bipolar cells: Reversible electron transfer
The voltammetric response of bipolar cells: Reversible electron transfer
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DOI：
10.1016/j.jelechem.2010.03.020
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发表时间：
2010-07-15
影响因子：
4.5
通讯作者：
Dryfe, Robert A. W.
中科院分区：
文献类型：
--
作者：
Plana, Daniela;Jones, Fran G. E.;Dryfe, Robert A. W.
描述了通过在总体恒电位控制下在两个半电池之间建立电连接而形成的双极电池的伏安响应。将用可逆氧化还原电对获得的实验数据与相应的两相传输问题的数值模拟进行比较，其中电荷传输可能受到氧化还原活性电对中的一个或两个氧化还原活性电对的传输的限制。还描述了将该系统扩展到更复杂的电子转移过程（特别是金属沉积）的初步实验。 (C) 2010 Elsevier B.V. 保留所有权利。
The voltammetric response of a bipolar cell, formed by making electrical connection between two half-cells under overall potentiostatic control, is described. Experimental data obtained with reversible redox couples are compared with numerical simulations of the corresponding two-phase transport problem, where charge transfer may be limited by the transport of either, or both, of the redox-active couples. Preliminary experiments on the extension of the system to more complex electron transfer processes, specifically metal deposition, are also described. (C) 2010 Elsevier B.V. All rights reserved.