Di(1-naphthyl) methanol ester of carboxylic acids for absolute stereochemical determination.

Di(1-naphthyl) methanol ester of carboxylic acids for absolute stereochemical determination.
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用于绝对立体化学测定的羧酸二(1-萘基)甲醇酯。

DOI:
10.1002/chir.22775
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发表时间:
2018
期刊:
影响因子:
2
通讯作者:
B. Borhan
B. Borhan
中科院分区:
化学4区
文献类型:
--
作者:
Jun Zhang;Wei Sheng;H. Gholami;T. Nehira;B. Borhan

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手性羧酸的绝对立体化学被确定为二(1-萘基)甲醇酯衍生物。计算评分的构象有利于P或M螺旋的萘基,能够激子耦合的圆二色性耦合,导致预测的立体化学的衍生羧酸。
The absolute stereochemistry of chiral carboxylic acids is determined as a di(1-naphthyl)methanol ester derivative. Computational scoring of conformations favoring either P or M helicity of the naphthyl groups, capable of exciton-coupled circular dichroic coupling, leads to a predicted stereochemistry for the derivatized carboxylic acids.
DOI: 10.1126/science.288.5470.1404
发表时间: 2000-05-26
期刊: SCIENCE
影响因子: 56.9
作者:
Zahn, S;Canary, JW
通讯作者: Canary, JW