CO2 = CO + O: Redox-Neutral Lactamization and Lactonization of C-H Bonds with CO2
CO2 = CO + O: Redox-Neutral Lactamization and Lactonization of C-H Bonds with CO2
复制标题
CO2 = CO O：氧化还原中性内酰胺化和 C-H 键与 CO2 的内酯化
作者：
Zhang Zhen;Ju Tao;Ye Jian-Heng;Yu Da-Gang
二氧化碳是一种无毒、廉价、容易获得的温室气体，是理想的羰基源，其功能类似于CO和氧化剂的结合(‘CO2=CO+O’)。我们通过在氧化还原中性甚至无过渡金属条件下与二氧化碳的C-H键的内酰化和内酯化的最新进展来强调这一概念。
Carbon dioxide, a nontoxic, cheap and readily available greenhouse gas, acts as the ideal carbonyl source with similar function as the combination of CO and oxidants (‘CO2= CO + O’). We highlight this concept with recent advances of the lactamization and lactonization of C–H bond with CO2under redox-neutral or even transition-metal-free conditions.