Systems of Alkali and Rare‐Earth Metal Fluorides
Systems of Alkali and Rare‐Earth Metal Fluorides
复制标题
DOI：
10.1002/chin.200006250
复制
发表时间：
2000-02
期刊：
影响因子：
--
通讯作者：
P. Fedorov
中科院分区：
文献类型：
--
作者：
P. Fedorov
综述了碱金属氟化物(Mf)和稀土氟化物(RF3)二元体系的实验相平衡数据。分析了化合物和非化学计量相的稳定性与R3+离子半径的关系。作为临界分析的结果，绘制了完整的Mf-Rf_3(M=Li，Na，K，Rb，Cs)相图。简要讨论了M=Ag、Tl、NH4化合物的形成以及与Mf、Rf_3的三元化合物的形成。
A survey is given of experimental phase equilibrium data from binary systems of alkali metal fluorides (MF) and lanthanide fluorides (RF3). The stability of compounds and nonstoichiometric phases is analyzed as a function of the R3+ ion radius. The complete series of MF–RF3 (M= Li, Na, K, Rb, Cs) phase diagrams are constructed as a result of a critical analysis. The formation of compounds for M= Ag, Tl, and NH4 and of ternary compounds with MF and RF3 are briefly discussed.