Transitions(1s2p)P03−(2p2)Pe3in He and(2s2p)P03−(2p2)Pe3inH−
Transitions(1s2p)P03−(2p2)Pe3in He and(2s2p)P03−(2p2)Pe3inH−
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DOI：
10.1103/physreva.2.1667
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发表时间：
1970-11
影响因子：
2.9
通讯作者：
A. K. Bhatia
中科院分区：
文献类型：
--
作者：
A. K. Bhatia
Precision calculations of the energies of the (2 p 2) P e 3 states of He and H− are carried out with a Hylleraas-type wave function and are the lowest variational results yet obtained. The associated wave functions are used to calculate the mass polarization of the state. With the reduced mass correction, the wave numbers of the transitions (1 s 2 p) P 0 3−(2 p 2) P e 3 in He and (2 s 2 p) P 0 3−(2 p 2) P e 3 in H− are found to be 312 222 and 3783 cm− 1, respectively. This former value is in disagreement with the experiment of Kruger (1930) who obtained 312 118 cm− 1. The discrepency between the experimental and theoretical values of 100 cm− 1 is large enough to encourage renewed experimental observation.
