TRANSITION ORGANOMETALLIC MEDIATED SYNTHESIS OF A MALONIC ESTER FROM CARBON-MONOXIDE
TRANSITION ORGANOMETALLIC MEDIATED SYNTHESIS OF A MALONIC ESTER FROM CARBON-MONOXIDE
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DOI：
10.1021/om00136a018
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发表时间：
1986-05-01
期刊：
影响因子：
2.8
通讯作者：
CUTLER, AR
中科院分区：
文献类型：
--
作者：
BODNAR, TW;CRAWFORD, EJ;CUTLER, AR
(j75-C5H5)(C0)2Fe（或Fp）有机金属体系及其膦或亚磷酸酯取代的衍生物已用于将连接一氧化碳转化为氧化有机分子的合成研究。 1, 2 烷氧基乙酰基铁配合物 1 的 C2 配体源自 CpFe (CO) 3+ 上的两个 CO 基团，因此选择性地转化为烷氧基甲基 2、烷氧基甲酰甲基 3 和甲酰甲基 4 配合物 (eq1)。这些复合物在质子解作用后分别产生乙酸酯、乙醇醛醚和乙醛。 3
The (j75-C5H5)(C0) 2Fe (or Fp) organometallic system and its phosphine-or phosphite-substituted derivatives have been used in synthetic studies for converting ligatedcarbon monoxide into oxygenated organic molecules. 1, 2 Alkoxyacetyl iron complexes 1, with their C2 ligand originating from two CO groups on CpFe (CO) 3+, accordingly have been transformed selectively into carbalkoxymethyl 2, alkoxy-formylmethyl 3, and formylmethyl 4 complexes (eq1). These complexes, in turn, upon protonolysis afford acetic acid ester, glycoaldehyde ether, and acetaldehyde, re-spectively. 3