The synthesis of diarylsulfones with simple arenes and K2S2O8 through double C-S bond formation.

The synthesis of diarylsulfones with simple arenes and K2S2O8 through double C-S bond formation.
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DOI:
10.1039/c4cc05964f
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发表时间:
2014-11
影响因子:
4.9
通讯作者:
Yiqing Yang;Zhang Chen;Yu Rao
Yiqing Yang;Zhang Chen;Yu Rao
中科院分区:
化学2区
文献类型:
--
作者:
Yiqing Yang;Zhang Chen;Yu Rao

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An unprecedented double C-S bond formation method has been developed to prepare both symmetric and unsymmetric diarylsulfones with simple arenes in a single step. This represents the first example that K2S2O8 can be employed as a highly effective sulfonating agent to synthesize diarylsulfones. The reaction demonstrates excellent reactivity, good functional group tolerance and high yields.