Structure of trans-3,3-dichloro-4-(alpha-chlorobenzyl)-1-methyl-5-phenyl-2-pyrrolidi none.

Structure of trans-3,3-dichloro-4-(alpha-chlorobenzyl)-1-methyl-5-phenyl-2-pyrrolidi none.
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反式-3,3-二氯-4-(α-氯苄基)-1-甲基-5-苯基-2-吡咯烷酮的结构。

DOI:
10.1107/s0108270191008533
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发表时间:
1992
期刊:
Acta crystallographica. Section C, Crystal structure communications
影响因子:
--
通讯作者:
DeShong,P
DeShong,P
中科院分区:
--
文献类型:
--
作者:
Parvez,M;Lander,SW;DeShong,P

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C18H16C13NO, Mr= 368.69, triclinic, P1, a= 10.360 (1), b= 10.397 (1), c= 10.810 (2) A, a= 60.84 (1),/3= 57.22 (1), y= 70.97 (1), V= 852 (1)~ 3, Z= 2, Dx= 1.437 Mgm-3, MoKte radiation,, 1= 0.71073 A,/z= 0.54 mm-1, F (000)= 380, T= 293 (1) K, R= 0.0287 for 2330 observed reflections with I> 3tr (/). The five-membered ring has an envelope conformation and the 4-(a-chlorobenzyl) and 5-phenyl groups are trans with respect to each other.Experimental. The title compound (2) was synthe-sized by radical cyclization of the allylic amide (1)