Synthesis and Functionality of Cyclophosphazene-Based Polymers
Synthesis and Functionality of Cyclophosphazene-Based Polymers
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环磷腈基聚合物的合成和功能
DOI：
10.1246/bcsj.74.1381
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发表时间：
2001
影响因子：
4
通讯作者：
T. Itaya
中科院分区：
文献类型：
--
作者：
Kenzo Inoue;T. Itaya
线性聚（有机磷腈）已被广泛研究，主要是将带有有机基团的无机-P=N-主链的结构与其性能和功能相关联。我们的兴趣集中在侧链、主链或作为中心核心和端基中含有环磷腈单元的相对新型聚合物。这些聚合物中的磷腈基团可以作为聚合物的改性位点，从而产生新的功能化材料。环磷腈的六个或更多个反应位点适合于制备星形聚合物或包括树枝状聚合物的超支化聚合物。最近与聚合物自组装相关的工作表明，一些有机环磷腈是构建超分子的有用基序，反映了环三（磷腈）的结构特征。在这篇综述中，我们描述了含有环三（磷腈）的聚合物的合成和功能。
Linear poly(organophosphazene)s have been widely investigated, mainly to correlate the structure of inorganic –P=N– backbone bearing organic groups with their properties and functionalites. Our interests have been directed to relatively new types of polymers containing a cyclophosphazene unit in the side chains, main chains, or as central core and end groups. The phosphazene groups in these polymers can serve as modification sites of polymers, leading to new functionalized materials. The six or more reactive sites of cyclophosphazenes are suitable for the preparation of star-shaped polymers or hyperbranched polymers including dendrimers. Recent works related with polymeric self-assembly showed that some organocyclophosphazenes are useful motifs for the construction of supramolecules, reflecting the structural features of the cyclotri(phosphazene)s. In this review, we describe the synthesis and functionalities of polymers containing cyclotri(phosphazene)s.
聚合物/无机胶囊颗粒的合成及热物性
DOI：
--
发表时间：
2009
期刊：
影响因子：
--
作者：
T. Sasaki;T. Uchida and K. Sakurai;佐々木隆
通讯作者：
佐々木隆