Enhanced conversion efficiencies of Cu2ZnSnS4-based thin film solar cells by using preferential etching technique

Enhanced conversion efficiencies of Cu2ZnSnS4-based thin film solar cells by using preferential etching technique
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DOI:
10.1143/apex.1.041201
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发表时间:
2008-04-01
影响因子:
2.3
通讯作者:
Motohiro, Tomoyoshi
Motohiro, Tomoyoshi
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Katagiri, Hironori;Jimbo, Kazuo;Motohiro, Tomoyoshi

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采用Cu、SnS和ZnS三种靶材,采用共溅射技术制备了Cu2ZnSnS4(CZTS)薄膜太阳电池。通过在形成CZTS层之后将涂覆Mo的钠钙玻璃衬底上的CZTS层浸泡在去离子水(DIW)中,首次获得了超过6.7%效率的基于CZTS的薄膜太阳能电池。通过电子探针X射线显微分析发现,DIW浸泡具有优先刻蚀的效果,其选择性地消除CZTS层中的金属氧化物颗粒。(C)2008年日本应用物理学会。
Cu2ZnSnS4 (CZTS) thin film solar cells have been fabricated by co-sputtering technique using three targets of Cu, SnS, and ZnS. CZTS-based thin film solar cells over 6.7% efficiency were obtained for the first time by soaking the CZTS layer on the Mo coated soda-lime glass substrate in deionized water (DIW) after forming the CZTS layer. It was found that DIW-soaking had the effect of preferential etching, which eliminated selectively metal oxide particles in the CZTS layer, by electron probe X-ray micro analysis. (C) 2008 The Japan Society of Applied Physics.