ACTIVATION AND ETA-2-COORDINATION OF ARENES - CRYSTAL AND MOLECULAR-STRUCTURE OF AN (ETA-2-HEXAFLUOROBENZENE)RHODIUM COMPLEX
ACTIVATION AND ETA-2-COORDINATION OF ARENES - CRYSTAL AND MOLECULAR-STRUCTURE OF AN (ETA-2-HEXAFLUOROBENZENE)RHODIUM COMPLEX
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DOI：
10.1039/c39890000928
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发表时间：
1989-07-15
影响因子：
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通讯作者：
PERUTZ, RN
中科院分区：
文献类型：
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作者：
BELT, ST;DUCKETT, SB;PERUTZ, RN
（Cp）Rh（PMe 3）（C2 H4），（1，Cp=η5-C5 H5）与苯的光解反应通过激光闪光光解检测到的瞬态η2-C6 F6络合物产生（Cp）Rh（PMe 3）（Ph）H;（1）与C6 F6的相应反应产生（C）Rh（PMe 3）（η2-C6 F6），其包含几乎平面的C6 F4单元，剩余的氟弯曲出平面43 °。
The photolytic reaction of (Cp)Rh(PMe3)(C2H4), (1, Cp=η5-C5H5) with benzene yields (Cp)Rh(PMe3)(Ph)H via a transient η2-C6F6 complex detected by laser flash photolysis; the corresponding reaction of (1) with C6F6 yields (C)Rh(PMe3)(η2-C6F6) which contains an almost planar C6F4 unit with the remaining fluorines bent out of the plane by 43 °.