(Acetylacetonato)(N,N,N',N'-tetramethylethylenediamine)copper(II) tetraphenylborate as a solvent basicity indicator.
(Acetylacetonato)(N,N,N',N'-tetramethylethylenediamine)copper(II) tetraphenylborate as a solvent basicity indicator.
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(乙酰丙酮)(N,N,N,N-四甲基乙二胺)四苯基硼酸铜(II)作为溶剂碱度指示剂。
DOI：
10.1246/bcsj.60.2286
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发表时间：
1987
影响因子：
4
通讯作者：
K. Sone
中科院分区：
文献类型：
--
作者：
R. W. Soukup;K. Sone
标题配合物[Cu(acac)(tmen)]BPh4是溶剂碱度的颜色指示剂，由于其不愿形成离子对，因此在非常弱的供体溶剂中比相应的高氯酸盐作用更好。配合物阳离子[Cu(acac)(tmen)]+在很强的供体溶剂中分解，但这些指示剂在使用时仍需谨慎。
The title complex, [Cu(acac)(tmen)]BPh4, is a color indicator for solvent basicity which serves better than the corresponding perchlorate in very weak donor solvents owing to its reluctance in ion-pair formation. The complex cation [Cu(acac)(tmen)]+ decomposes in very strong donor solvents, but these indicators may still be used in them with some care.