Fluoridation of heteroaromatic iodonium salts -: experimental evidence supporting theoretical prediction of the selectivity of the process

Fluoridation of heteroaromatic iodonium salts -: experimental evidence supporting theoretical prediction of the selectivity of the process
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DOI:
10.1039/b000868k
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发表时间:
2000-01-01
影响因子:
4.9
通讯作者:
Widdowson, DA
Widdowson, DA
中科院分区:
化学2区
文献类型:
--
作者:
Martín-Santamaría, S;Carroll, MA;Widdowson, DA

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实验结果表明,除苯并[b]呋喃外,一系列芳基杂碘盐被氟离子取代对芳环具有区域选择性。
Theoretical prediction, that the nucleophilic substitution of a range of arylheteroaryliodonium salts by fluoride ion is regioselective for the aryl ring with the exception of benzo[b]furan, are borne out by experimental observation.