A Mild Benzannulation through Directed Cycloaddition Reactions
A Mild Benzannulation through Directed Cycloaddition Reactions
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DOI：
10.1002/anie.201200917
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发表时间：
2012-01-01
影响因子：
16.6
通讯作者：
Harrity, Joseph P. A.
中科院分区：
文献类型：
--
作者：
Kirkham, James D.;Butlin, Roger J.;Harrity, Joseph P. A.
简单如ABC：与传统方法相比，炔基硼烷环加成可以在极其温和和有效的反应歧管内被底物引导以组装芳族二氟硼烷（参见方案）。芳族硼烷很容易转化成一系列有用的产物。
Simple as ABC: Alkynyl borane cycloadditions can be substrate-directed to assemble aromatic difluoroboranes within an extremely mild and efficient reaction manifold compared to that of traditional methods (see scheme). The aromatic boranes are readily transformed into a range of useful products.