Synthesis and Characterisation of a Novel Thermoresponsive Dendronized Monomer Bearing Azobenzene Moiety

Synthesis and Characterisation of a Novel Thermoresponsive Dendronized Monomer Bearing Azobenzene Moiety
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DOI:
10.4028/www.scientific.net/amr.989-994.494
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发表时间:
2014-07
期刊:
Advanced Materials Research
影响因子:
--
通讯作者:
C. Yang;W. Xiao;Enxiang Liang;Ying Lu;Gangyong Li
C. Yang;W. Xiao;Enxiang Liang;Ying Lu;Gangyong Li
中科院分区:
其他
文献类型:
--
作者:
C. Yang;W. Xiao;Enxiang Liang;Ying Lu;Gangyong Li

文献摘要

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合成了一种新型的含偶氮苯结构的温度响应性树枝状单体甲基丙烯酸4-(4′-(3,4,5-三(2-(2-甲氧基乙氧基)乙氧基)苄氧基)苯偶氮)苄酯。中间体和树枝化单体的化学结构经FTIR和1H NMR确证。研究了这些中间体和树枝化单体的相转变行为。这些中间化合物和树枝化单体表现出明显的可逆温敏相变行为。
Novel thermoresponsive dendronized monomer bearing azobenzene moiety, 4-(4′-(3, 4, 5-tris (2-(2-methoxyethoxy) ethoxy) benzyloxy) phenylazo) benzyl methacrylate, has been successfully synthesized. The chemical structures of intermediate compounds and dendronized monomer were confirmed by FTIR and 1H NMR. The phase transition behaviors of these intermediate compounds and dendronized monomer were investigated. These intermediate compound and dendronized monomer showed remarkably reversible thermoresponsive phase transition behaviors.