Complex and liquid hydrides for energy storage
Complex and liquid hydrides for energy storage
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DOI：
10.1007/s00339-016-9881-5
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发表时间：
2016-04-01
影响因子：
2.7
通讯作者：
Zuettel, Andreas
中科院分区：
文献类型：
--
作者：
Callini, Elsa;Atakli, Zuleyha Oezlem Kocabas;Zuettel, Andreas
复合氢化物储氢的研究始于1996年Boris Bogdanovic发现Ti作为NaAlH4中的氢吸附催化剂。从那时起，大量不同形式和组合的新型复合氢化物材料被合成和表征，并且从那时起，关于复合氢化物的性质和合成方法的知识有了巨大的发展。活跃在复合氢化物领域的研究小组的很大一部分是国际能源协议任务32的合作者。本文报道了复合氢化物研究领域的重要问题，即硼氢化物的合成、复合氢化物的热力学、尺寸和约束的影响、氢吸附机制和复合氢化物复合材料以及液体复合氢化物的性质。本文是多个小组合作的成果，是对近期成果的精彩总结。
The research on complex hydrides for hydrogen storage was initiated by the discovery of Ti as a hydrogen sorption catalyst in NaAlH4 by Boris Bogdanovic in 1996. A large number of new complex hydride materials in various forms and combinations have been synthesized and characterized, and the knowledge regarding the properties of complex hydrides and the synthesis methods has grown enormously since then. A significant portion of the research groups active in the field of complex hydrides is collaborators in the International Energy Agreement Task 32. This paper reports about the important issues in the field of complex hydride research, i.e. the synthesis of borohydrides, the thermodynamics of complex hydrides, the effects of size and confinement, the hydrogen sorption mechanism and the complex hydride composites as well as the properties of liquid complex hydrides. This paper is the result of the collaboration of several groups and is an excellent summary of the recent achievements.