Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds
Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds
复制标题
二硅烷杂环络合物用于羰基化合物的氢硅烷还原的非常高的催化剂效率
DOI：
10.1039/c8cc04780d
复制
发表时间：
2018
影响因子：
4.9
通讯作者：
Nagashima Hideo
中科院分区：
文献类型：
--
作者：
Tahara Atsushi;Sunada Yusuke;Takeshita Takashi;Inoue Ryoko;Nagashima Hideo
一种双硅杂钌无环配合物（1）对醛、酮氢化硅烷还原为硅醚和仲、叔酰胺还原为相应的胺表现出极高的催化活性。提出了σ-CAM机理来解释该活性。
A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.