Preparation and functionalization of multilayer fullerenes (carbon nano-onions)

Preparation and functionalization of multilayer fullerenes (carbon nano-onions)
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DOI:
10.1002/chem.200500517
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发表时间:
2006-01-01
影响因子:
4.3
通讯作者:
Echegoyen, L
Echegoyen, L
中科院分区:
化学2区
文献类型:
--
作者:
Rettenbacher, AS;Elliott, B;Echegoyen, L

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碳纳米洋葱(CNOS)是一种在很大程度上仍未被探索的碳同素异形体。这些独特的碳结构的良好性质推动了这一领域的研究工作,但在其制备、衍生化、分离和表征方面仍存在许多技术问题。在本文中,我们报道了cNOS的制备、部分纯化、多官能化和增溶。由于只有一篇先前发表的描述CNO功能化的简短通信([1]),本工作是迄今为止对CNO功能化和表征最全面的描述。
Carbon nano-onions (CNOs) represent a still largely unexplored carbon allotrope. Promising properties of these unique carbon structures are driving the research efforts in this area, but many technical problems remain in their preparation, derivatization, separation and characterization. In this article, we report the preparation, partial purification, and multiple functionalization and solubilization of CNOs. With only one priorly published short communication([1]) describing CNO functionalization, the present work is the most comprehensive description of CNO functionalization and characterization to date.