Methods for Debrominating 4,5-Dibromopentanyl Glycosides

Methods for Debrominating 4,5-Dibromopentanyl Glycosides
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4,5-二溴戊基糖苷的脱溴方法

DOI:
10.1080/07328309608005425
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发表时间:
1996
影响因子:
1
通讯作者:
B. Fraser
B. Fraser
中科院分区:
化学4区
文献类型:
--
作者:
J. Merritt;J. S. Debenham;B. Fraser

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摘要分别用碘化锌、碘化钐和碘化钠对4,5-二溴戊基糖苷进行脱溴反应,(再)生成正戊烯基糖苷。试剂的选择取决于底物的反应性以及其上的保护基团。
Abstract Debromination of 4,5-dibromopentanyl glycosides to (re)generate n-pentenyl glycosides has been accomplished using zinc, samarium(II) iodide, and sodium iodide, respectively. The choice of reagent is dependent upon the reactivity of the substrate, as well as the protecting groups thereon.