A New Class of S-Bridged Hexanuclear Complexes with Aminoethanethiolate Ligands. Formation and Structural Characterization of [PdII2{NiII(aet)2}x{PdII(aet)2}4-x]Br4 (x = 0-4; aet = 2-Aminoethanethiolate)
A New Class of S-Bridged Hexanuclear Complexes with Aminoethanethiolate Ligands. Formation and Structural Characterization of [PdII2{NiII(aet)2}x{PdII(aet)2}4-x]Br4 (x = 0-4; aet = 2-Aminoethanethiolate)
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一类新型 S 桥六核配合物与氨基乙硫醇配体。
DOI：
10.1021/ic00083a006
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发表时间：
1994
影响因子：
4.6
通讯作者：
K. Okamoto
中科院分区：
文献类型：
--
作者：
T. Konno;Kunio Yonenobu;J. Hidaka;K. Okamoto
[M（aet）z2]与Pd Ⅱ在水溶液中反应，然后加入NaBr，得到一类新的S-桥六核配合物[Pd 2 {M（aet）2 } 4 ] Br 4·6 H2O（aet=氨基乙硫醇盐; M=Ni Ⅱ（1），Pd Ⅱ（2））. [Pd（aet）2 ]与Ni Ⅱ的反应也得到了S-桥六环配合物[Pd 2 {Ni（aet）2 } xePd（aet）2 } 4-x ] Br4.6H2O（x= 0-4）（3），这表明双齿-N，S配体aet很容易从Pd Ⅱ转移到Ni Ⅱ配位层
The reactions of [M(aet)z 2 with Pd II in water, followed by the addition of NaBr, gave a new class of S-bridged hexanuclear complexes [Pd 2 {M(aet) 2 } 4 ] Br 4 .6H 2 O (aet=aminoethanethiolate; M=Ni II (1), Pd II (2)). The same reaction of [Pd(aet) 2 ] with Ni II led to the formation of a mixture of S-bridged hexanuclcar complexes [Pd 2 {Ni(aet) 2 } x ePd(aet) 2 } 4-x ] Br 4 .6H 2 O (x= 0-4) (3), which implies that the didentate-N,S ligand aet readily transfers from the Pd II to the Ni II coordination sphere