Intramolecular cation-π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

Intramolecular cation-π interactions control the conformation of nonrestricted (phenylalkyl)pyridines
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DOI:
10.1039/b716937j
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发表时间:
2008-01-01
影响因子:
4.9
通讯作者:
Fossey, John S.
Fossey, John S.
中科院分区:
化学2区
文献类型:
--
作者:
Richter, Isabella;Minari, Jusaku;Fossey, John S.

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NOEsy和荧光光谱显示构象柔性(苯基烷基)吡啶转化为相应的n -甲基碘化吡啶导致分子内pi堆积。
NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular pi-stacking.