Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds
Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds
复制标题
金催化苯衍生物与供体/受体取代的重氮化合物的对位选择性C-H键烷基化
DOI：
10.1039/c7cc05649d
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发表时间：
2017-09-18
影响因子：
4.9
通讯作者：
Zhang, Junliang
中科院分区：
文献类型：
--
作者：
Ma, Ben;Wu, Jiaojiao;Zhang, Junliang
本文报道了一种金催化的未活化芳烃与α-芳基-α-重氮酯的高位点选择性C（sp（2））-H官能化反应，其中α-芳基-α-重氮酯的芳环上带有吸电子取代基作为诱导基团。此外，诱导基团对于进一步的合成转化是有用的。
Herein, we report a gold-catalyzed highly site-selective C(sp(2))-H functionalization of unactivated arenes with alpha-aryl-alpha-diazoesters with electron-withdrawing substituents as induced groups on aryl rings. Furthermore, the induced groups are useful for further synthetic transformations.