"If Pigs Could Fly" Chemistry: A Tutorial on the Principle of Microscopic Reversibility
"If Pigs Could Fly" Chemistry: A Tutorial on the Principle of Microscopic Reversibility
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DOI：
10.1002/anie.200804566
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发表时间：
2009-01-01
影响因子：
16.6
通讯作者：
Blackmond, Donna G.
中科院分区：
文献类型：
--
作者：
Blackmond, Donna G.
透过一个黑暗的玻璃：最近的几个自催化反应模型的起源同手性提出的方法，其中一种对映异构体的产品可能会重新转化为其他在一个封闭的系统中的循环反应。这些模型被发现违反了微观可逆性原理，这是一个强大的工具，即使在远离平衡的条件下，也可以评估拟议的反应网络的可逆性。
Through a glass darkly: Several recent autocatalytic reaction models for the origin of homochirality have suggested ways in which one enantiomer of the product might be reconverted into the other by a recycling reaction in a closed system. These models are revealed to violate the principle of microscopic reversibility, a powerful tool for assessing the plausibility of proposed reaction networks even at far‐from‐equilibrium conditions.