Isolation and characterization of a carbene derivative of La@C82
Isolation and characterization of a carbene derivative of La@C82
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DOI：
10.1021/ja0316115
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发表时间：
2004-06-09
影响因子：
15
通讯作者：
Yamamoto, K
中科院分区：
文献类型：
--
作者：
Maeda, Y;Matsunaga, Y;Yamamoto, K
La@C82与2-金刚烷-2，3-[~3H]-二氮杂环丙烷的光化学反应生成加合物2，La@C82(Ad)。化合物2的结构经电子自旋共振、MS和UV-−-Vis-−近红外光谱确证，并首次报道了一种面内单金属富勒烯衍生物的X-射线晶体结构。
The photochemical reaction of La@C82with 2-adamantane-2,3-[3H]-diazirine affords adduct2, La@C82(Ad), in a quantitative and highly selective manner. The structure of compound2is confirmed by ESR, MS, and UV−vis−NIR spectroscopies, and the first X-ray crystallographic characterization of an endohedral monometallofullerene derivative is reported.