Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation
Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation
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DOI：
10.1039/b517668a
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发表时间：
2006-01-01
影响因子：
4.9
通讯作者：
Ariga, Katsuhiko
中科院分区：
文献类型：
--
作者：
Hill, Jonathan P.;Wakayama, Yutaka;Ariga, Katsuhiko
苯酚取代的卟啉TDtBHPP的氧化态与其结构耦合，使得其2-电子氧化导致分子的共平面化和其吸附在金属基底上的表面自组装结构的基本稳定。
The oxidation state of the phenol-substituted porphyrin TDtBHPP is coupled with its structure so that its 2-electron oxidation leads to a coplanarization of the molecule and a substantial stabilization of its surface self-assembled structures adsorbed at metal substrates.