Product identification and distribution from the oscillatory versus non-oscillatory palladium(II) iodide-catalysed oxidative carbonylation of phenylacetylene
Product identification and distribution from the oscillatory versus non-oscillatory palladium(II) iodide-catalysed oxidative carbonylation of phenylacetylene
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DOI：
10.1016/j.molcata.2007.12.020
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发表时间：
2008-04-02
影响因子：
--
通讯作者：
Wright, Allen R.
中科院分区：
文献类型：
--
作者：
Grosjean, Christophe;Novakovicb, Katarina;Wright, Allen R.
研究了苯乙炔的氧化羧基化，以确定导致振荡与非振荡行为的产物分布和反应条件。对产物及其分布进行了明确的鉴定，之后发现导致振荡行为的反应条件会产生高转化率和更具选择性的产物分布。 (C) 2008 Elsevier B.V. 保留所有权利。
The oxidative carborylation of phenylacetylene was studied in order to determine the production distribution and reaction conditions which result in oscillatory versus non-oscillatory behaviour. Unambiguous identification of the products and their distribution was undertaken, after which, it was found that reaction conditions which result in oscillatory behaviour produce high conversions, and more selective product distribution. (C) 2008 Elsevier B.V. All rights reserved.