EFFECT OF PRESSURE ON CHARGE-TRANSFER COMPLEXES IN SOLUTION .2. COMPLEXES FORMED BETWEEN IONS AND BETWEEN IONS AND NEUTRAL MOLECULES
EFFECT OF PRESSURE ON CHARGE-TRANSFER COMPLEXES IN SOLUTION .2. COMPLEXES FORMED BETWEEN IONS AND BETWEEN IONS AND NEUTRAL MOLECULES
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DOI：
10.1021/j100646a019
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发表时间：
1972-01-01
影响因子：
--
通讯作者：
SCUDDER, JA
中科院分区：
文献类型：
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作者：
EWALD, AH;SCUDDER, JA
离子与中性分子（碘化钠与三硝基苯、硼酸托吡酯与六甲基苯、五甲氧羰基环戊二烯钾与三硝基苯）形成的EDAC对稳定常数和CT最大值的影响不大。这些发现的压力效应，并为中性-中性配合物的研究较早，定性解释的变化的溶剂化的组分和配合物所带来的压力变化。
EDAC formed between ions and neutral molecules (sodium iodide and trinitrobenzene, tropylium tetrafluoro-borate and hexamethylbenzeue, and potassium pentamethoxycarbonylcyclopentadienylide and trinitrobenzene) showed little effect of pressure on the stability constant and on the CT maximum. The pressure effects found for these, and for the neutral-neutral complexes investigated earlier, are interpreted qualitatively in terms of the change of solvation of the components and the complexes brought about by the change in pressure.