Neutral coordination frameworks with host–guest properties constructed by dicopper(II) units and 4,7-phenanthroline
Neutral coordination frameworks with host–guest properties constructed by dicopper(II) units and 4,7-phenanthroline
复制标题
DOI：
10.1016/j.poly.2003.09.014
复制
发表时间：
2004
期刊：
影响因子：
2.6
通讯作者：
Hui Huang;Shu‐Yan Yu;Hong-bo Liu;Mei Shi
中科院分区：
文献类型：
--
作者：
Hui Huang;Shu‐Yan Yu;Hong-bo Liu;Mei Shi
[Cu 2（O2 CR）4] [R=Me（1），Ph（2）]与4，7-菲咯啉反应生成中性配位骨架{[Cu 2（O2 CR）4]（C12 N2 H8）} n，对溶剂分子表现出包结行为，通过改变双金属单元的赤道配体，可以调控配位聚合物的孔道大小和主客体性质.
Reaction of [Cu2(O2CR)4] [R=Me(1), Ph(2)] with 4,7-phenanthroline produced neutral coordination frameworks {[Cu2(O2CR)4](C12N2H8)}nshowing inclusion behavior toward solvent molecules; through variation of the equatorial ligands of the dimetal units, the channels size and host–guest properties of the coordination polymers can be controlled.