Self-assembly growth and electron work function of copper phthalocyanine films on indium tin oxide glass

Self-assembly growth and electron work function of copper phthalocyanine films on indium tin oxide glass
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氧化铟锡玻璃上铜酞菁薄膜的自组装生长和电子逸出功

DOI:
10.1016/j.apsusc.2011.10.143
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发表时间:
2012-02
影响因子:
6.7
通讯作者:
Changquan Li
Changquan Li
中科院分区:
材料科学1区
文献类型:
--
作者:
Mingshan Xue;Zhonghao Jiang;Wen Li;Guangli Bi;Junfei Ou;Fajun Wang;Changquan Li

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有机半导体材料正在成为不仅具有科学意义而且在新能源领域具有潜在应用前景的课题。在这项研究中,铜酞菁(CuPc)薄膜作为一种优异的有机半导体,通过电沉积在氧化铟锡玻璃上自组装生长,并使用各种技术研究了其结构和电子性能。结果表明,得到了有序的α型结晶CuPc薄膜。发现CuPc薄膜的电子功函数随着薄膜厚度的增加而减小,这明显依赖于表面形貌。了解 CuPc 薄膜的这些行为对于设计相关光电器件具有重要意义。
Organic semiconductor materials are becoming a promising subject of not only scientific interest but also potential applications in the field of new energy resources. In this study, the copper phthalocyanine (CuPc) films as an excellent organic semiconductor were self-assembly grown on indium tin oxide glass by electrodeposition, the structural and electronic properties were investigated using various techniques. The results demonstrated that ordered α-form crystalline CuPc films were obtained. The decrease of electron work function of CuPc films with the increase of film thickness was found, which was obviously dependent on the surface morphology. The understanding of these behaviors of CuPc films will be significant for designing related photoelectric devices.
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