A Simple Graphical Check of Consistency for Zero Length Column Desorption Curves
A Simple Graphical Check of Consistency for Zero Length Column Desorption Curves
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DOI：
10.1002/ceat.201500634
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发表时间：
2016-06-01
影响因子：
2.1
通讯作者：
Brandani, Stefano
中科院分区：
文献类型：
--
作者：
Brandani, Stefano
零长度柱（ZLC）系统的质量平衡导致一个非常简单的检查，可以用来确保实验曲线的内部一致性。这是基于在c/c（0）vs. Ft图上以不同流速运行的报告实验，其中F是体积流速。所提出的方法是适用于两个不同的结果，从文献中，可以用来识别，在一种情况下，数据是不一致的。结果导致一个重要的建议：任何未来的贡献报告ZLC曲线应包括c/c（0）与Ft图，可以确认结果的内部一致性，并表明实验是在平衡或动力学控制下进行。
The mass balance for a zero length column (ZLC) system leads to a very simple check which can be used to ensure internal consistency of the experimental curves. This is based on reporting experiments run at different flow rates on a c/c(0) vs. Ft plot, where F is the volumetric flow rate. The proposed method is applied to two different sets of results from the literature and can be used to identify that in one case the data are inconsistent. The results lead to an important recommendation: any future contribution reporting ZLC curves should include the c/c(0) vs. Ft plot which can confirm the internal consistency of the results and indicate if the experiments are carried out under equilibrium or kinetic control.