A binuclear iron-thiolate catalyst for electrochemical hydrogen production in aqueous micellar solution.
A binuclear iron-thiolate catalyst for electrochemical hydrogen production in aqueous micellar solution.
复制标题
一种双核硫醇铁催化剂，用于在胶束水溶液中电化学产氢。
作者：
F. Quentel;Guillaume Passard;F. Gloaguen
取代铁硫酸盐配合物[Fe(2)(μ-bdt)(CO)(4){P(OMe)(3)}(2)] （bdt=苯二硫酸盐）是十二烷基硫酸钠水溶液中电化学制氢的活性催化剂，具有较高的表观速率常数4×10(6) M(-1) s（-1）。与pH值为3的标准氢电极相比，催化质子还原的半峰电位小于负-0.6 V。伏安数据与扩散控制的电极反应速率一致。提出了一种由硫代铁催化剂的快速质子化开始的机理。在稀HCl溶液中，法拉第效率接近100%，但在醋酸存在下电解时，催化活性在12次左右就衰减了。
The substituted iron-thiolate complex [Fe(2)(μ-bdt)(CO)(4){P(OMe)(3)}(2)] (bdt=benzenedithiolate) is an active catalyst for electrochemical hydrogen production in aqueous sodium dodecyl sulfate solution, with a high apparent rate constant of 4×10(6) M(-1) s(-1). The half-peak potential for catalysis of proton reduction is less negative than -0.6 V versus the standard hydrogen electrode at pH 3. Voltammetric data are consistent with the rate of electrode reaction controlled by diffusion. A mechanism that begins with the rapid protonation of the iron-thiolate catalyst is proposed. The Faradaic efficiency in diluted HCl solutions is close to 100%, but the catalytic activity decayed after about twelve turnovers when electrolysis was carried out in the presence of acetic acid.
影响因子：
46.2
作者：
Gloaguen F;Rauchfuss TB
通讯作者：
Rauchfuss TB
可见光分解水：用于制氢的纳米光电阴极。
DOI：
10.1002/anie.200906262
发表时间：
2010
期刊：
Angewandte Chemie (International ed. in English)
影响因子：
--
作者：
Nann T
通讯作者：
Nann T