Catalytic Conversion of Dinitrogen into Ammonia under Ambient Reaction Conditions by Using Proton Source from Water.
Catalytic Conversion of Dinitrogen into Ammonia under Ambient Reaction Conditions by Using Proton Source from Water.
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DOI：
10.1002/asia.201701067
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发表时间：
2017-10
期刊：
影响因子：
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通讯作者：
Yoshiaki Tanabe;Kazuya Arashiba;K. Nakajima;Y. Nishibayashi
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文献类型：
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作者：
Yoshiaki Tanabe;Kazuya Arashiba;K. Nakajima;Y. Nishibayashi
钼催化的分子二氮转化为氨在环境反应条件下已实现通过使用质子源在原位产生的从钼催化的水的氧化与可见光和光敏剂的组合。预置反应体系是光合细菌固氮的一种新模式。
Molybdenum-catalyzed conversion of molecular dinitrogen into ammonia under ambient reaction conditions has been achieved by using a proton source generated in situ from the ruthenium-catalyzed oxidation of water in combination with visible light and a photosensitizer. The preset reaction system is considered as a new model for the nitrogen fixation by photosynthetic bacteria.