Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions
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DOI:
10.1039/b411633j
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发表时间:
2004-01-01
影响因子:
4.9
通讯作者:
Fukuzumi, S
Fukuzumi, S
中科院分区:
化学2区
文献类型:
--
作者:
Hayashi, H;Ogo, S;Fukuzumi, S

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使用水溶性钌水溶液催化剂[(eta(6)-C6 Me 6)Ru-II(L)(OH 2)] SO 4(L = 2,2 '-联吡啶或4,4'-二甲氧基-2,2 '-联吡啶),在酸性条件(pH 2.5-5.0)下,在水中将二氧化碳(P(H-2/CO2)= 5.5/2.5 MPa)加氢为甲酸(HCOOH)。
Hydrogenation of carbon dioxide (P(H-2/CO2) = 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions ( pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [(eta(6)-C6Me6) Ru-II(L)(OH2)] SO4 ( L = 2,2'-bipyridine or 4,4'-dimethoxy-2, 2'- bipyridine).