The codeposition of alumina and titania with copper

The codeposition of alumina and titania with copper
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氧化铝、二氧化钛与铜的共沉积

DOI:
10.1007/bf02664222
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发表时间:
1971
期刊:
Metallurgical Transactions
影响因子:
--
通讯作者:
F. K. Sautter
F. K. Sautter
中科院分区:
--
文献类型:
--
作者:
E. Chen;G. Lakshminarayanan;F. K. Sautter

文献摘要

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研究了酸性铜电解液中Al_2O_3和TiO_2的共沉积过程,考察了溶液pH、电解液中颗粒浓度、添加剂以及氧化物颗粒晶相的性质。发现氧化物的引入是可能的,不需要添加剂,只要氧化物颗粒具有良好的晶型,如α-Al_2O_3和金红石型二氧化钛。报道了一种将γ-Al_2O_3颗粒部分转化为α形式,从而使氧化物适合共沉积的技术。
The codeposition of Al2O3and TiO2from the acid copper electrolyte was investigated with respect to solution pH, particle concentration in the electrolyte, addition agents and the nature of the crystalline phase of the oxide particles. The incorporation of oxides was found possible without the need of addition agents, provided the oxide particles are of the favorable crystalline form as α-Al2O3and rutile TiO2. A technique is reported whereby the γ-Al2O3particles are partially transformed to the α-form making the oxide suitable for codeposition.