Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) π-alkene complexes that contain a sterically hindered o-biphenylphosphine ligand

Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) π-alkene complexes that contain a sterically hindered o-biphenylphosphine ligand
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DOI:
10.1039/b914632f
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发表时间:
2009-01-01
影响因子:
4.9
通讯作者:
Widenhoefer, Ross A.
Widenhoefer, Ross A.
中科院分区:
化学2区
文献类型:
--
作者:
Brown, Timothy J.;Dickens, Marina G.;Widenhoefer, Ross A.

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本文报道了一系列阳离子金π-烯烃配合物{[P(t-Bu)(2)o-联苯]Au(π-烯烃)} + SbF_(6-),并对其中三个配合物进行了X射线晶体学分析。
A number of cationic gold pi-alkene complexes of the form {[P(t-Bu)(2)o-biphenyl]Au(pi-alkene)} +SbF6- were isolated and three were analyzed by X-ray crystallography.