Silver-Catalyzed Aerobic Oxidative Decarboxylative Coupling of Arylpropiolic Acids with H-Phosphine Oxides: Mild and Facile Synthesis of beta-Oxophosphine Oxides
Silver-Catalyzed Aerobic Oxidative Decarboxylative Coupling of Arylpropiolic Acids with H-Phosphine Oxides: Mild and Facile Synthesis of beta-Oxophosphine Oxides
复制标题
银催化芳基丙酸与 H-氧化膦的有氧氧化脱羧偶联：温和且简便地合成 β-氧代氧化膦
DOI：
10.1002/ejoc.201500587
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发表时间：
2015
影响因子：
2.8
通讯作者：
Wang Honggen
中科院分区：
文献类型：
--
作者：
Zeng Yao-Fu;Tan Dong-Hang;Lv Wen-Xin;Li Qingjiang;Wang Honggen
以空气为终端氧化剂，研究了银催化芳基丙炔酸与氢氧化膦的氧化脱羧偶联反应。反应在温和条件下顺利进行，以中等至良好的产率得到β-氧代膦氧化物。进行了初步的机理研究。
A silver‐catalyzed oxidative decarboxylative coupling reaction of arylpropiolic acids withH‐phosphine oxides by using air as the terminal oxidant was developed. The reaction proceeds smoothly under mild conditions to give β‐oxophosphine oxides in moderate to good yields. Preliminary mechanistic studies were conducted.