Enhancement of Excess Electron Transfer Efficiency in DNA Containing a Phenothiazine Donor and Multiple Stable Phenanthrenyl Base Pairs

Enhancement of Excess Electron Transfer Efficiency in DNA Containing a Phenothiazine Donor and Multiple Stable Phenanthrenyl Base Pairs
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DOI:
10.1002/chem.201301983
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发表时间:
2013-08-26
影响因子:
4.3
通讯作者:
Leumann, Christian J.
Leumann, Christian J.
中科院分区:
化学2区
文献类型:
--
作者:
Roethlisberger, Pascal;Wojciechowski, Filip;Leumann, Christian J.

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EET增长欧姆:以吩噻嗪为电子供体、菲为电子载体、5-溴尿嘧啶为电子陷阱的DNA双链体中存在过量电子转移(EET)。增加菲基碱基对的数目增加EET效率。
EET grown ohm: Excess electron transfer (EET) was observed within a DNA duplex containing π-stacked phenothiazine as an electron donor, phenanthrenes as electron carriers and 5-bromouracil as an electron trap. Increasing the number of phenanthrenyl base pairs increased EET efficiency.