Neutral anion receptors: design and application
Neutral anion receptors: design and application
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DOI：
10.1039/a707529d
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发表时间：
1998-02-21
影响因子：
4.9
通讯作者：
Reinhoudt, DN
中科院分区：
文献类型：
--
作者：
Antonisse, MMG;Reinhoudt, DN
在20世纪60年代后期开发出合成阳离子受体之后，直到最近十年才开始开发合成中性阴离子受体。不同阴离子结合基团如酰胺、脲部分或刘易斯酸性金属中心的组合和预组织导致以高选择性强烈结合无机阴离子的受体分子。与中性阳离子配体结合，得到了用于无机盐络合的双配位受体。阴离子受体的分子络合性质已经被转换成膜分离过程和用于选择性阴离子检测的传感器中的宏观性质。
After the development of synthetic cation receptors in the late 1960s, only in the past decade has work started on the development of synthetic neutral anion receptors. Combination and preorganization of different anion binding groups, like amides, urea moieties, or Lewis acidic metal centers lead to receptor molecules that strongly bind inorganic anions with high selectivity. Combined with neutral cation ligands, ditopic receptors were obtained for the complexation of inorganic salts. The molecular complexation properties of anion receptors has been transduced into macroscopic properties in membrane separation processes and in sensors for selective anion detection.