A water-stable lanthanide-coordination polymer with free Lewis site for fluorescent sensing of Fe3

A water-stable lanthanide-coordination polymer with free Lewis site for fluorescent sensing of Fe3
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一种具有游离路易斯位点的水稳定性镧系配位聚合物,用于 Fe3 的荧光传感

DOI:
10.1016/j.cclet.2018.06.014
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发表时间:
2019
影响因子:
9.1
通讯作者:
Bu Xianhe
Bu Xianhe
中科院分区:
化学1区
文献类型:
--
作者:
Wang Wenhe;Gao Qiang;Li Xiaoyu;Wang Jianhong;Wang Chaopeng;Zhang Yinghui;Bu Xianhe

文献摘要

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以Tb3+离子和H2L (5-(4h -1,2,4-三唑-4-基)苯-1,3-二羧酸)为配体,在溶剂热条件下构建了新型荧光配位聚合物NKU-115,具有较高的溶剂稳定性和水稳定性。荧光研究表明,nku -115在水溶液中对Fe3+表现出荧光猝灭反应,并分析了猝灭机理。
A new fluorescent coordination polymer (NKU-115) was constructed under solvothermal condition based on Tb3+ion and H2L (5-(4H-1,2,4-triazol-4-yl) benzene-1,3-dicarboxylic acid) ligand, featuring high solvent and water stability. Luminescent investigations revealed thatNKU-115shows fluorescence quenching response toward Fe3+in aqueous solution and the mechanism of quenching was analyzed.