Interweaving 3D network with double helical tubes filled by 1D coordination polymer chains.
Interweaving 3D network with double helical tubes filled by 1D coordination polymer chains.
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DOI：
10.1021/ic049363g
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发表时间：
2004-09
影响因子：
4.6
通讯作者：
E. Yang;Jian Zhang;Zhao-ji Li;Song Gao;Yao Kang;Yu-Biao Chen;Y. Wen;Yuangen Yao
中科院分区：
文献类型：
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作者：
E. Yang;Jian Zhang;Zhao-ji Li;Song Gao;Yao Kang;Yu-Biao Chen;Y. Wen;Yuangen Yao
苯六甲酸、4，4 '-联吡啶和Cu（CH（3）COO）（2）·H（2）O的水热反应生成了一种由三种配位聚合物基序相互贯穿的新型三维超分子结构。两个独立的[[Cu（2）（mellitate）（4，4 '-bpy）（H（2）O）（2）]（2）（-）]三维聚合物结合螺旋亚结构交织成三维网络与双链螺旋管主机一维线性聚合物[Cu（4，4'-bpy）（H（2）O）（4）]（2+）]（n）。
The hydrothermal reaction of mellitic acid, 4,4'-bipydine, and Cu(CH(3)COO)(2).H(2)O gave rise to a novel 3D supramolecular architecture interpenetrated by three types of coordination polymer motifs. Two independent [[Cu(2)(mellitate)(4,4'-bpy)(H(2)O)(2)](2)(-)] 3D polymers incorporating helical substructures were interwoven into a 3D network with double-stranded helical tubes that host 1D linear polymers [Cu(4,4'-bpy)(H(2)O)(4)](2+)](n).