Syntheses and structures of six compounds that contain the sodium anion
Syntheses and structures of six compounds that contain the sodium anion
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DOI：
10.1080/00958979808047191
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发表时间：
1998-01-01
影响因子：
1.9
通讯作者：
Dye, JL
中科院分区：
文献类型：
--
作者：
Huang, RH;Huang, SZ;Dye, JL
得到了钠盐（IUPAC，钠盐）、K+(12-crown-4)(2)-Na- (I)、Na+(cryptand[2.2.1])Na- (II)、Rb+(18-crown-6)Na-的晶体结构。CH3NH2 (III), K+(18-crown-6) Na-。2 (CH3NH2)。3 (18-crown-6) (IV), c +(穴状配体(3.2.2))Na - (V),和李(+)(2)(TMPAND) (2) (Na)(2)。（CH3NH2）（VI），其中TMPAND为5,12,17-三甲基-1,5,9,12,17-五氮杂环[7.5.5]十一烷)。介绍了其合成、处理和晶体生长技术，并与其它碱类化合物的性质和结构进行了比较。
Crystal structures have been obtained for the sodide (IUPAC, natride) salts, K+(12-crown-4)(2)-Na- (I), Na+(cryptand[2.2.1])Na- (II), Rb+(18-crown-6)Na-. CH3NH2 (III), K+(18-crown-6) Na-. 2(CH3NH2). 3(18-crown-6) (IV), Cs+(cryptand[3.2.2])Na- (V), and (Li+)(2)(TMPAND)(2)(Na-)(2).(CH3NH2)(VI), in which TMPAND is 5,12,17-trimethyl-1,5,9,12,17-pentaazabicyclo [7.5.5] nonadecane). The synthesis, handling and crystal growth techniques are described and the properties and structures are compared with those of other alkalides.