Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q = 3,5-di-tert-butyl-benzoquinone.
Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q = 3,5-di-tert-butyl-benzoquinone.
复制标题
将两个非无害配体组合成异构体复合物 [Pt(pap)(m)Q(n)](0)（pap = 苯基氮杂吡啶，Q = 3,5-二叔丁基苯醌。
DOI：
10.1039/b902645b
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发表时间：
2009
影响因子：
4
通讯作者：
I. Hartenbach
中科院分区：
文献类型：
--
作者：
B. Sarkar;R. Hübner;Roberto Pattacini;I. Hartenbach
据报道，含有两个非无害配体的铂同分异构配合物。配体中固有的配位不对称性使得分离两种不同位置异构体成为可能。 X 射线晶体学的结果用于调用这些配合物中常见的结构氧化态相关性。借助紫外-可见-近红外和 EPR 光谱电化学对氧化还原过程进行了讨论和解释。
Isomeric complexes of platinum, which contain two non-innocent ligands are reported. The built-in coordination asymmetry in the ligands makes it possible to separate two different positional isomers. Results from X-ray crystallography is used to invoke the popular structure oxidation state correlation in these complexes. The redox processes are discussed and interpreted with the help of UV-vis-NIR and EPR spectroelectrochemistry.