A carbon material as a strong protonic acid
A carbon material as a strong protonic acid
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DOI：
10.1002/anie.200453947
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发表时间：
2004-01-01
影响因子：
16.6
通讯作者：
Domen, K
中科院分区：
文献类型：
--
作者：
Hara, M;Yoshida, T;Domen, K
磺基芳烃的不完全碳化会产生一种碳材料，这种碳材料由带有SO 3 H基团的多环芳烃碳片组成（见图）。这种不溶性固体酸在乙酸乙酯的生成、乙酸环己酯的水解和2，3-二甲基-2-丁烯的水合中表现出非常高的活性。
Incomplete carbonization of sulfoaromatic hydrocarbons results in a carbon material that consists of small polycyclic aromatic carbon sheets with attached SO 3 H groups (see picture). This insoluble solid acid exhibits remarkably high activity in the formation of ethyl acetate, the hydrolysis of cyclohexyl acetate, and the hydration of 2, 3-dimethyl-2-butene.