Efficient and chemoselective reduction of carbonyl compounds with supported gold catalysts under transfer hydrogenation conditions.

Efficient and chemoselective reduction of carbonyl compounds with supported gold catalysts under transfer hydrogenation conditions.
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DOI:
10.1039/b807608a
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发表时间:
2008-07
影响因子:
4.9
通讯作者:
Fang-Zheng Su;Lin He;J. Ni;Yong Cao;Heyong He;Kangnian Fan
Fang-Zheng Su;Lin He;J. Ni;Yong Cao;Heyong He;Kangnian Fan
中科院分区:
化学2区
文献类型:
--
作者:
Fang-Zheng Su;Lin He;J. Ni;Yong Cao;Heyong He;Kangnian Fan

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一种新的非均相催化转移氢化(CTH)体系,由不易燃的负载型Au催化剂沿着以异丙醇为供氢体组成,被证明能有效地化学选择性还原多种芳香酮和醛为相应的醇。
A new heterogeneous catalytic transfer hydrogenation (CTH) system, consisting of a non-flammable supported Au catalyst along with 2-propanol as the hydrogen donor, was proven to be effective for chemoselective reduction of a wide range of aromatic ketones and aldehydes to the corresponding alcohols.