Cell-free studies of monoterpene and sesquiterpene biosynthesis.
Cell-free studies of monoterpene and sesquiterpene biosynthesis.
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单萜和倍半萜生物合成的无细胞研究。
DOI：
10.1042/bst0110510
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发表时间：
1983
影响因子：
3.9
通讯作者：
Cane,DE
中科院分区：
文献类型：
--
作者：
Cane,DE
烯丙基焦磷酸盐是合成环单萜和倍半萜的重要前体。最近的工作在我们的实验室中使用无细胞酶系统从微生物和高等植物已经帮助澄清了许多的主要烯丙基焦磷酸，香叶基和法呢基焦磷酸，单萜和倍半萜代谢物，分别重排和环化的关键机制的细节。
Allylic pyrophosphates have been recognized for many years as the key precursors of cyclic monoterpenes and sesquiterpenes. Recent work in our laboratories using cell-free enzyme systems from both micro-organisms and higher plants has helped to clarify many of the key mechanistic details of the rearrangement and cyclization of the primary allylic pyrophosphates, geranyl and farnesyl pyrophosphate, to monoterpene and sesquiterpene metabolites, respectively.