Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond.: A kinetic study
Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond.: A kinetic study
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DOI：
10.1021/jo048656o
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发表时间：
2004-12-10
影响因子：
3.6
通讯作者：
Lanzalunga, O
中科院分区：
文献类型：
--
作者：
Baciocchi, E;Gerini, MF;Lanzalunga, O
研究了邻苯二甲酰亚胺N-氧自由基（PINO）与一系列取代苯酚的OH键反应的动力学。测定了反应选择性和氘动力学同位素效应。动力学溶剂效应的信息也得到了与苯酚作为底物。
The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH3CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.