Palladium(0)-mediated desymmetrization of meso tetraols: an approach to the C3-C17 bis-oxane segment of phorboxazoles A and B.
Palladium(0)-mediated desymmetrization of meso tetraols: an approach to the C3-C17 bis-oxane segment of phorboxazoles A and B.
复制标题
钯 (0) 介导的内消旋四醇去对称化：一种研究佛波唑唑 A 和 B 的 C3-C17 双恶烷片段的方法。
DOI：
10.1021/ol0354775
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发表时间：
2003
期刊：
影响因子：
5.2
通讯作者：
Burke,StevenD
中科院分区：
文献类型：
--
作者：
Lucas,BrianS;Burke,StevenD
meso-Tetraol bis(allylic acetates)2and5were synthesized via two-directional chain elongation. A palladium-mediated, ligand-controlled desymmetrization provided the desired bis-oxanes in greater than 98% ee. Bis-oxanes1and4represent potential synthetic intermediates for the C3−C17 subunits of phorboxazoles A and B.
